An autocatalytic radical chain pathway in formation of an iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol

作者：Morimoto Yuma; Lee Yong Min; Nam Wonwoo^*; Fukuzumi Shunichi

来源：Chemical Communications, 2013, 49(25): 2500-2502.

DOI：10.1039/c3cc38727e

Evidence of an autocatalytic radical chain pathway has been reported in formation of a non-heme iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol in acetonitrile at 298 K. The radical chain reaction is initiated by hydrogen abstraction from isopropanol by the iron(IV)-oxo complex.

• 出版日期2013