Diastereoselective synthesis of meso-pillar[6]arenes by bridging between hydroquinone units in an alternating up-and-down manner

作者：Ogoshi Tomoki^*; Demachi Kazuki; Masaki Kae; Yamagishi Tada aki

来源：Chemical Communications, 2013, 49(38): 3952-3954.

DOI：10.1039/c3cc41592a

We report the first synthesis of bridged pillararenes. Meso-form pillar[6]arenes were diastereo-selectively formed by bridging units of a per-hydroxylated pillar[6]arene in an alternating up-and-down manner with dialkyldichlorosilanes.

• 出版日期2013