A New 4-Connected Co(II) Coordination Framework With an Uncommon Two-Fold Interpenetrating Net: Synthesis, Structure and Luminescence Property

作者：Guo Feng^*

来源：Journal of Inorganic and Organometallic Polymers and Materials, 2009, 19(3): 406-409.

DOI：10.1007/s10904-009-9272-x

• Coordination polymer
• Co(II)
• Crystal structure
• Luminescence

The coordination polymer [Co(pbc)(2)(H(2)O)](n)(Hpbc = 3-Pyrid-4-ylbenzoic acid) was prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, FTIR spectra and element analysis. X-ray diffraction analysis reveals that the pbc(-) ligands act as diconnectors to link two Co(II) centers and adopt a two coordination mode: mu (2)-N, O and mu (2)-N, O, O to form infinite wavy cobalt-carboxylate chains along the bc plane. Furthermore, compound, [Co(pbc)(2)(H(2)O)](n), shows intense photoluminescence at room temperature.

• 出版日期2009-9
• 单位德州学院