Optical characterization, 1.5 mu m emission and IR-to-visible energy upconversion in Er3+-doped fluorotellurite glasses

作者：Rodriguez Mendoza U R^*; Lalla E A; Caceres J M; Rivera Lopez F; Leon Luis S F; Lavin V

来源：Journal of Luminescence, 2011, 131(6): 1239-1248.

DOI：10.1016/j.jlumin.2011.02.020

• Oxyfluoride glass
• Rare earth
• Optical properties
• Energy conversion

The optical properties of Er3+ ions in a novel glass based on TeO2-PbF2-AlF3 oxyfluoride tellurites have been investigated using steady-state and time-resolved spectroscopies as a function of the rare-earth doping concentration. Basic optical characterizations have been performed measuring and calculating the absorption and emission spectra and the cross-sections, the Judd-Ofelt intensity parameters, the radiative probabilities and the fluorescence decays and lifetimes. Special attention has been devoted to the broad I-4(13/2) I-4(15/2) emission transition at around 1.53 mu m since, with a wide broadening of around 70 nm and a relative long lifetime of around 3 ms compared to others glass hosts, it shows potential applications in the design of erbium-doped fiber amplifiers. The absorption, the stimulated emission and the gain cross-sections of this transition have been obtained and compared with that obtained in different hosts. Finally, infrared-to-visible upconversion processes exciting at around 800 nm have been analyzed and different mechanisms involved in the energy conversion have been proposed.

• 出版日期2011-6