Anthraquinone-Based Intramolecular Charge-Transfer Compounds: Computational Molecular Design, Thermally Activated Delayed Fluorescence, and Highly Efficient Red Electroluminescence

作者：Zhang, Qisheng; Kuwabara, Hirokazu; Potscavage, William J., Jr.; Huang, Shuping; Hatae, Yasuhiro; Shibata, Takumi; Adachi, Chihaya^*

来源：Journal of the American Chemical Society, 2014, 136(52): 18070-18081.

DOI：10.1021/ja510144h

• LIGHT-EMITTING-DIODES
• DENSITY-FUNCTIONAL THEORY
• ELECTRON-TRANSFER
• EXCITED-STATES
• TEMPERATURE-DEPENDENCE
• ACCEPTOR BIPHENYLS
• CU(I) COMPLEXES
• EMISSION COLOR
• DONOR
• LUMINESCENT

Red fluorescent molecules suffer from large, non-radiative internal conversion rates (k(IC)) governed by the energy gap law. To design efficient red thermally activated delayed fluorescence (TADF) emitters for organic light-emitting diodes (OLEDs), a large fluorescence rate (k(F)) as well as a small energy difference between the lowest singlet and triplet excited states (Delta E-ST) is necessary. Herein, we demonstrated that increasing the distance between donor (D) and acceptor (A) in intramolecular-charge-transfer molecules is a promising strategy for simultaneously achieving small Delta E-ST and large k(F). Four D-Ph-A-Ph-D-type molecules with an anthraquinone acceptor, phenyl (Ph) bridge, and various donors were designed, synthesized, and compared with corresponding D-A-D-type molecules. Yellow to red TADF was observed from all of them. The k(F) and Delta E-ST values determined from the measurements of quantum yield and lifetime of the fluorescence and TADF components are in good agreement with those predicted by corrected time-dependent density functional theory and are approximatively proportional to the square of the cosine of the theoretical twisting angles between each subunit. However, the introduction of a Ph-bridge was found to enhance k(F) without increasing Delta E-ST. Molecular simulation revealed a twisting and stretching motion of the NC bond in the D-A-type molecules, which is thought to lower Delta E-ST and k(F) but raise k(IC), that was experimentally confirmed in both solution and doped film. OLEDs containing D-Ph-A-Ph-D-type molecules with diphenylamine and bis(4-biphenyl)amine donors demonstrated maximum external quantum efficiencies of 12.5% and 9.0% with emission peaks at 624 and 637 nm, respectively.

• 出版日期2014-12-31