Nitrogen-containing chitosan-based carbon as an electrode material for high-performance supercapacitors

作者：Sliwak Agata; Diez Noel; Miniach Ewa; Gryglewicz Grazyna^*

来源：Journal of Applied Electrochemistry, 2016, 46(6): 667-677.

DOI：10.1007/s10800-016-0955-z

• Chitosan
• CO2 activation
• Nitrogen-doped porous carbon
• Pseudocapacitance
• Supercapacitor

Nitrogen-containing activated carbons were prepared from chitosan, a widely available and inexpensive biopolysaccharide, by a simple procedure and tested as electrode material in supercapacitors. The physical activation of chitosan chars with CO2 led to carbons with a very high nitrogen content (up to 5.4 wt%) and moderate surface areas (1000-1100 m(2) g(-1)). Only chitosan-based activated carbons with a similar microporous structure were considered in this study to evaluate the effect of the nitrogen content and distribution on their electrochemical performance. The N-containing activated carbons were tested in two- and three-electrode supercapacitors using an aqueous electrolyte (1 M H2SO4), and they exhibited superior surface capacitance (19.5 A mu F cm(-2)) and pseudocapacitance compared to a commercial activated carbon with a negligible nitrogen content and similar microporosity. The low oxygen content and the presence of stable quaternary nitrogen improved the charge propagation on the chitosan-based carbons, which was confirmed by the high capacity retention of 83 %. The chitosan-based carbons exhibited excellent cyclic stability and maintained 100 % of their capacitance after 5000 charge/discharge cycles at a current density of 1 A g(-1). These results demonstrate the suitability of chitosan-based carbons for application in energy storage systems.

• 出版日期2016-6