A tris(2-quinolylmethyl)amine scaffold that promotes hydrogen bonding within the secondary coordination sphere

作者：Moore Cameron M; Szymczak Nathaniel K^*

来源：Dalton Transactions, 2012, 41(26): 7886-7889.

DOI：10.1039/c2dt30406f

A new quinolyl-based ligand presents three amide functionalities to act as hydrogen-bond accepting groups to a metal-bound substrate at a well-defined distance. As a confirmation of the design strategy, CH3CN coordinated to copper(II) participates in CH-O interactions in the solid state and in solution.

• 出版日期2012