Stepwise activation of %26quot;non-innocent%26quot; Cp* substituents - a Cp* based cascade reaction

作者：Stubenhofer Markus; Lassandro Giuliano; Balazs Gabor; Timoshkin Alexey Y; Scheer Manfred^*

来源：Chemical Communications, 2012, 48(58): 7262-7264.

DOI：10.1039/c2cc32690f

Reactions of Cp* substituted pentelidene complexes with the primary phosphine Cp*PH2 yield novel polycyclic phosphorus/arsenic and carbon containing cage compounds via cascade-like reactions. These reactions include a sequence of nucleophilic addition reactions, intramolecular hydrophosphination (partially hydroarsination) reactions, retro-Diels-Alder reactions with Cp*H elimination and subsequent [2+4]-cycloadditions.

• 出版日期2012