Asymmetric anthracene-based blue host materials: synthesis and electroluminescence properties of 9-(2-naphthyl)-10-arylanthracenes

作者：Wee Kyung Ryang; Han Won Sik; Kim Ju Eun; Kim Ae Li; Kwon Soonnam; Kang Sang Ook^*

来源：Journal of Materials Chemistry, 2011, 21(4): 1115-1123.

DOI：10.1039/c0jm02877k

A series of bulky aryl-substituted asymmetric anthracene blue host materials, 9-(2-naphthyl)-10-(3-(1-naphthyl) phenyl) anthracene, where phenyl was varied from H (5a), Me (5b), Ph (5e), and 1-Naph (5f) at the 6-position and Me (5c) at the 2-position, was synthesized by Suzuki coupling reaction between 10-(2-naphthyl) anthracene-9-boronic acid and 1-(3-iodophenyl) naphthalene derivatives. A less bulky aryl-substituted anthracene, 9-(2-naphthyl)-10-(2,5-diphenyl) phenyl) anthracene (5d), was also synthesized for comparison. All asymmetric anthracenes showed high glass transition temperatures in the range of 84-153 degrees C. The photophysical and electrochemical properties in solution showed that the substituent at the 10-positions of the anthracene unit did not influence the blue emission of 420 nm and HOMO-LUMO energy level (5.5-2.5 eV). However, a gradual decrease of bathochromic shift in solid state PL was observed from the increaseg of the substituent bulkiness, exhibiting 5e (18 nm) <= 5f (19 nm) <= 5c (25 nm) <= 5b (26 nm) < 5a (30 nm) < 5d (41 nm), respectably. When 5a was used as a blue host material in the multilayered device structure of ITO/DNTPD/NPD/host:dopant (9%)/PyPySPyPy/LiF/Al, enhanced OLED device performance was observed, showing a luminous current efficiency of 9.9 cd A(-1), power efficiency of 6.3 lm W-1 at 20 mA cm(-2), deep blue color coordinates of (0.14, 0.18), and a 932 h device lifetime at L-0 = 3000 cd m(-2).

• 出版日期2011