A novel fluorene-containing oligomer with relative high photoluminescence quantum efficiency

作者:Jiang, Hong-Ji; Feng, Jia-Chun; Wang, Hong-Yu; Wei, Wei; Huang, Wei*
来源:Journal of Fluorine Chemistry, 2006, 127(7): 973-976.
DOI:10.1016/j.jfluchem.2006.03.005

摘要

A novel oligomer (F1) based on 2,4-difluorobenzene and trifluorene was prepared and characterized. The experimental results showed that the new trifluorene containing 2,4-difluorobenzene had relative high photoluminescence quantum efficiency, up to 71.6%, compared with 42% of tfifluorene (F0), and its maximum absorption and emission spectra took on some abnormal characteristics, which could both be attributed to the unique function of fluorine.