A new 3D pillared-layer porous framework with intersecting open channels in the Co/triazolate/carboxylate system: Synthesis, structure and magnetism

作者：Miao, Shao-Bin; Ji, Bao-Ming^*; Wang, Yu-Fang; Li, Zhao-Hao; Deng, Dong-Sheng; Xu, Chun-Ying; Zhou, Le

来源：Inorganic Chemistry Communications, 2015, 62: 47-50.

DOI：10.1016/j.inoche.2015.10.024

• 1,3-Di-(1,2,4-triazole-4-yl)benzene
• Coordination polymers
• Crystal structure
• Magnetism

A new Co(II) coordination polymer, namely [Co-6(btc)(4)(dtb)(2)(H2O)(3)](n) (1) (H(3)btc = 1,3,5-benzenetricarboxylic acid, dtb = 1,3-di-(1,2,4-triazole-4-yl)benzene), has been synthesized by combining the mixed ligands of H3btc and dtb with Co(Ac)(2)center dot 4H(2)O under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 feature a 3D open framework with intersecting channels based on Co-btc(3-) layers and btc(3-) and dtb pillars. The magnetic property of the complex has also been investigated at room temperature.

• 出版日期2015-12
• 单位洛阳师范学院; 西北农林科技大学