A bridged low band gap A-D-A quaterthiophene as efficient donor for organic solar cells

作者：Baert Francois; Cabanetos Clement; Leliege Antoine; Kirchner Eva; Segut Olivier; Aleveque Olivier; Allain Magali; Seo Gijun; Jung Sungyeop; Tondelier Denis; Geffroy Bernard; Roncali Jean; Leriche Philippe; Blanchard Philippe^*

来源：Journal of Materials Chemistry C, 2015, 3(2): 390-398.

DOI：10.1039/c4tc02212b

alpha,omega-Bis(dicyanovinyl)quaterthiophene 1 with a median 4,4-diethyl-4H-cyclopenta[2,1-b:3,4-b']-dithiophene has been synthesized. UV-Vis absorption data show that the covalent bridging of the inner 2,2'-bithiophene leads to a significant reduction of the HOMO-LUMO gap essentially due to an increase of the HOMO level as confirmed by electrochemical and theoretical results. X-ray diffraction analysis of a single crystal of 1 shows that except for the out-of-plane ethyl groups, the conjugated system displays a quasi-planar geometry while the molecular packing exhibits strong pi-stacking interactions and multiple short intermolecular contacts. Quaterthiophene 1 has been used as active donor material in organic solar cells of various architectures including bi-layer planar hetero-junctions and hybrid co-evaporated bulk hetero-junctions with C-60 as electron acceptor material. A maximum conversion efficiency of 4.30% is obtained with a hybrid co-evaporated device. These results are discussed in terms of structure-properties relationships with reference to the open-chain parent alpha,omega-bis(dicyanovinyl) quaterthiophene 2.

• 出版日期2015
• 单位中国地震局