A gigantic polyoxozirconate with visible photoactivity

作者：Xu, Tingting; Hou, Xudong; Wang, Yang; Zhang, Jun; Zhang, Junxiang; Liu, Bo^*

来源：Dalton Transactions, 2017, 46(31): 10185-10188.

DOI：10.1039/c7dt02013a

• POLYOXOMETALATE CHEMISTRY
• CRYSTAL-STRUCTURE
• OXYGEN VACANCY
• ZIRCONIUM
• CLUSTERS
• NANOPARTICLES
• NANOCLUSTER
• STABILITY
• TITANIUM
• CATIONS

We present a gigantic polyoxozirconate nanocluster (Zr18O21(mu(2)-OH)(2)(OOCPh)(28)), involving 6, 7 and 8-coordinated Zr atoms. It exhibits visible light driven photocatalytic activity for H-2 evolution. The current results could represent a prelude of polyoxozirconate-based photocatalysis.

• 出版日期2017-8-21
• 单位中国科学技术大学