A method for the formation of Pt metal nanoparticle arrays using nanosecond pulsed laser dewetting

作者：Owusu Ansah Ebenezer; Horwood Corie A; El Sayed Hany A; Birss Viola I; Shi Yujun J^*

来源：Applied Physics Letters, 2015, 106(20): 203103.

DOI：10.1063/1.4921528

Nanosecond pulsed laser dewetting of Pt thin films, deposited on a dimpled Ta (DT) surface, has been studied here in order to form ordered Pt nanoparticle (NP) arrays. The DT substrate was fabricated via a simple electrochemical anodization process in a highly concentrated H2SO4 and HF solution. Pt thin films (3-5 nm) were sputter coated on DT and then dewetted under vacuum to generate NPs using a 355 nm laser radiation (6-9 ns, 10Hz). The threshold laser fluence to fully dewet a 3.5 nm thick Pt film was determined to be 300 mJ/cm(2). Our experiments have shown that shorter irradiation times (<= 60 s) produce smaller nanoparticles with more uniform sizes, while longer times (>60 s) give large nanoparticles with wider size distributions. The optimum laser irradiation time of 1 s (10 pulses) has led to the formation of highly ordered Pt nanoparticle arrays with an average nanoparticle size of 2663 nm with no substrate deformation. At the optimum condition of 1 s and 500 mJ/cm(2), as many as 85% of the dewetted NPs were found neatly in the well-defined dimples. This work has demonstrated that pulsed laser dewetting of Pt thin films on a pre-patterned dimpled substrate is an efficient and powerful technique to produce highly ordered Pt nanoparticle arrays. This method can thus be used to produce arrays of other high-melting-point metal nanoparticles for a range of applications, including electrocatalysis, functionalized nanomaterials, and analytical purposes.

• 出版日期2015-5-18