A highly reduced cyanogen ligand derived from cyanide reductive coupling

作者:Fox Alexander R; Cummins Christopher C*
来源:Chemical communications, 2012, 48(25): 3061-3063.
DOI:10.1039/c2cc17212g

摘要

The synthesis, structure, and spectroscopic features of a bimetallic cyanogen complex obtained from the reductive coupling of cyanide by a niobium(IV) precursor are described, and a mechanism for the coupling reaction is proposed based on DFT calculations.

  • 出版日期2012