Multiple conformational changes of beta-tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

作者：Koide Taro; Youfu Katsuyuki; Saito Shohei; Osuka Atsuhiro^*

来源：Chemical communications, 2009, (40): 6047-6049.

DOI：10.1039/b910167e

beta-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28] hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Mobius aromaticity.

• 出版日期2009