A Combinatorial Investigation of Fe-Si-Zn Thin Film Negative Electrodes for Li-Ion Batteries

作者:MacEachern L*; Dunlap R A; Obrovac M N
来源:Journal of the Electrochemical Society, 2015, 162(1): A229-A234.
DOI:10.1149/2.1051501jes

摘要

Thin-film Fe-Si-Zn libraries were investigated as negative electrode materials for Li-ion batteries using combinatorial and high-throughput techniques. X-ray diffraction and electron microprobe measurements were used to characterize the library structure. A large amorphous region exists in Si-rich compositions of this system. The electrochemistry of numerous compositions of Fe-Si-Zn materials was determined near room temperature. Both Zn and Fe additions to Si were found to suppress the formation of Li15Si4 during cycling.

  • 出版日期2015