Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand

作者：Hicks Jamie; Jones Cameron^*

来源：Organometallics, 2015, 34(11): 2118-2121.

DOI：10.1021/om501233f

A series of low-coordinate, high-spin, mono- dinuclear cobalt(I) complexes beating an extremely bulky amide (L '' = N(Ar*)(SiPh3); Ar* = C8H2{C(H)Ph-2}(2)Me-2,6,4) ligand have been synthesized and characterized, These include the first example of a neutral two-coordinate Cobalt(I) complex, [L '' Co(IPriMe)] (IPriMe) = :C{N(Pr-i)C(Me)=}(2)), which has a near-linear cobalt coordination geometry.

• 出版日期2015-6-8