MPI-DING reference glasses for in situ microanalysis: New reference values for element concentrations and isotope ratios

作者：Jochum Klaus Peter^*; Stoll Brigitte; Herwig Kirstin; Willbold Matthias; Hofmann Albrecht W; Amini Marghaleray; Aarburg Susanne; Abouchami Wafa; Hellebrand Eric; Mocek Beate; Raczek Ingrid; Stracke Andreas; Alard Olivier; Bouman Claudia; Becker Stefan; Duecking Marc; Braetz Helene; Klemd Reiner; de Bruin Deon; Canil Dante; Cornell Dave; de Hoog Cees Jan; Dalpe Claude; Danyushevsky Leonid; Eisenhauer Anton; Gao Yongjun; Snow Jonathan E; Goschopf NOra; Gunther D

来源：Geochemistry Geophysics Geosystems, 2006, 7(2): Q02008.

DOI：10.1029/2005GC001060

• MPI-DING glasses
• reference values
• isotopes
• in situ microanalysis
• geochemistry : radiogenic isotope geochemistry
• geochemistry : major and trace element geochemistry
• geochemistry : instruments and techniques

[1] We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties ( at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Association of Geoanalysts (IAG). The reference values were derived from the results of 16 independent techniques, including definitive ( isotope dilution) and comparative bulk ( e. g., INAA, ICPMS, SSMS) and microanalytical ( e. g., LA-ICPMS, SIMS, EPMA) methods. Agreement between two or more independent methods and the use of definitive methods provided traceability to the fullest extent possible. We also present new and recently published data for the isotopic compositions of H, B, Li, O, Ca, Sr, Nd, Hf, and Pb. The results were mainly obtained by high-precision bulk techniques, such as TIMS and MC-ICPMS. In addition, LA-ICPMS and SIMS isotope data of B, Li, and Pb are presented.

• 出版日期2006-2-15
• 单位中国极地研究中心