A Bench-Stable Pd Catalyst for the Hydroarylation of Fullerene with Boronic Acids

作者：Mori Susumu; Nambo Masakazu; Chi Liang Chen; Bouffard Jean; Itami Kenichiro^*

来源：Organic Letters, 2008, 10(20): 4609-4612.

DOI：10.1021/ol801936j

A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C(60) with an arylboronic acid in the presence of a catalytic amount of Pd(2-PyCH=NPh)(OCOC(6)F(5))(2) in H(2)O/1,2-Cl(2)C(6)H(4) at room temperature furnishes the hydroarylation product (Ar-C(60)-H) in good yield with high selectivity. This complex possesses high catalytic activity paired with bench stability in the solid state.

• 出版日期2008-10-16