摘要

In this paper, a 3D thermal runaway (TR) propagation model is built for a large format lithium ion battery module. The 3D TR propagation model is built based on the energy balance equation. Empirical equations are utilized to simplify the calculation of the chemical kinetics for TR, whereas equivalent thermal resistant layer is employed to simplify the heat transfer through the thin thermal layer. The 3D TR propagation model is validated by experiment and can provide beneficial discussions on the mechanisms of TR propagation. According to the modeling analysis of the 3D model, the TR propagation can be delayed or prevented through: 1) increasing the TR triggering temperature; 2) reducing the total electric energy released during TR; 3) enhancing the heat dissipation level; 4) adding extra thermal resistant layer between adjacent batteries. The TR propagation is successfully prevented in the model and validated by experiment. The model with 3D temperature distribution provides a beneficial tool for researchers to study the TR propagation mechanisms and for engineers to design a safer battery pack.