A ruthenium biimidazole-like anion receptor with two chelating N-H center dot center dot center dot O intramolecular hydrogen bonds

作者：Mo, Hao Jun; Chao, Hsiu Yi^*; Ye, Bao Hui

来源：Inorganic Chemistry Communications, 2013, 35: 100-103.

DOI：10.1016/j.inoche.2013.06.004

• Anion receptor
• Biimidazole
• Intramolecular hydrogen bond
• Ruthenium

A new ruthenium biimidazole-like anion receptor featuring two "chelating" N-H-O intramolecular hydrogen bonds, [Ru(bPY)(2)(DNBbimH(2))](PF6)(2) (2 center dot(PF6)(2)) (bpy = 2,2'-bipyridine; DNBbimH(2) = 5,5t,6,6t-tetramethyl-7,7'-dinitro-2,2'-bibenzimidazole), has been synthesized. Its anion-binding ability towards different anions in acetonitrile has been studied.

• 出版日期2013-9
• 单位中山大学