Asymmetric preparation of polysubstituted cyclopentanes by synergistic Pd(0)/amine catalyzed formal [3+2] cycloadditions of vinyl cyclopropanes with enals

作者:Laugeois Maxime; Ponra Sudipta; Ratovelomanana Vidal Virginie; Michelet Veronique; Vitale Maxime R
来源:Chemical communications, 2016, 52(30): 5332-5335.
DOI:10.1039/c6cc01775d

摘要

The stereocontrolled [3+2] cycloaddition reaction of vinyl cyclopropanes with enals has been accomplished by merging organocatalysis with palladium(0) catalysis.

  • 出版日期2016