A Structural study of the intermolecular interactions of tyramine with some pi-acceptors: Quantification of biogenic amines based on charge-transfer complexation

作者：Refat Moamen S; Saad Hosam A; Adam Abdel Majid A; Eldaroti Hala H

来源：Russian Journal of General Chemistry, 2015, 85(1): 185-191.

DOI：10.1134/S1070363215010326

• biogenic amines
• tyramine
• charge-transfer complex
• thermal decomposition

In this paper, we report the synthesis and characterization of four CT complexes of Ty with picric acid (PA), chloranilic acid (CLA), quinol (QL), and 1,3-dinitrobenzene (DNB), and present their thermal decomposition behavior. These complexes were structurally characterized to interpret the behavior of interactions using elemental analysis; IR and H-1 NMR spectroscopy. Finally, the thermal behavior of the obtained complexes and the kinetic thermodynamic parameters (E*, A, Delta S*, Delta H*, and Delta G*) were also investigated using Coats-Redfern and Horowitz-Metzger equations.

• 出版日期2015-1