Determination of organic compounds in landfill leachates treated by Fenton-Adsorption

作者：Ramirez Sosa Dorian R; Castillo Borges Elba R; Mendez Novelo Roger I^*; Sauri Riancho Maria R; Barcelo Quintal Manuel; Marrufo Gomez Jose M

来源：Waste Management, 2013, 33(2): 390-395.

DOI：10.1016/j.wasman.2012.07.019

• Landfill
• Advanced oxidation process
• Fenton
• Leachates
• Organic compounds

The objective of this study was to identify the organic compounds removed from the leachate when treated with Fenton-Adsorption by gas chromatography coupled to mass spectrometry (GC-MS) in order to identify toxic compounds that could be harmful for the environment or human health.
The physicochemical characterization of the raw leachate was carried out before and after the Fenton-Adsorption process. The effluent from each stage of this process was characterized: pH, Biological Oxygen Demand (BOD5), Chemical Oxygen Demand (COD), Total Organic Carbon (TOC), Total Carbon (TC), Inorganic Carbon (IC), Total Solids (TS), Total Suspended Solids (TSS) and Color. The organic compounds were determined by GC-MS.
The removal of COD and color reached over 99% in compliance with the Mexican Standard NOM-001-SEMARNAT-1996, which establishes the maximum permissible limits for contaminants present in wastewater discharges to water and national goods. The chromatographic analysis from the Fenton-Adsorption effluent proved that this treatment removed more than 98% of the organic compounds present in the initial sample. The mono (2-ethylhexyl) ester 1,2-benzenedicarboxylic acid persisted, although it is not considered as toxic compound by the NOM-052-SEMARNAT-2005. Therefore, the treated effluent can be safely disposed of into the environment.

• 出版日期2013-2