Macroscopic derivation of the kinetic mass-action law

作者：Pekar Miloslav^*

来源：Reaction Kinetics, Mechanisms and Catalysis, 2010, 99(1): 29-35.

DOI：10.1007/s11144-009-0101-6

• Mass-action
• Reaction rate
• Thermodynamic polynomial
• Thermodynamics

Using several reaction examples with experimentally determined rate equations, traditional mass-action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass-action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.

• 出版日期2010-2