Autocatalytic sonolysis of iron pentacarbonyl in room temperature ionic liquid [BuMeIm][Tf2N]

作者：Lartigue Lenaic; Pflieger Rachel; Nikitenko Sergey I^*; Guari Yannick; Stievano Lorenzo; Sougrati Moulay T; Larionova Joulia

来源：Physical Chemistry Chemical Physics, 2011, 13(6): 2111-2113.

DOI：10.1039/c0cp01670e

The autocatalytic sonochemical reaction of Fe(CO)(5) decomposition in [BuMeIm][Tf2N] provides iron nanoparticles in higher yields than in tetralin. Such a difference is explained by the higher decomposition of the intermediate Fe-3(CO)(12) according to the two-sites model of the sonochemical reactions and the specific properties of the ionic liquid.

• 出版日期2011