摘要

Free-radical generated at C-7 position of indole derivative bearing N-(3 '-chloroallyl) group prompted a regioselective intramolecular cyclization to furnish pyrroloindoline derivative, through the more favorable 5-exo-trig cyclization mode. The pyrroloindoline compound smoothly rearranged to pyrroloquinoline under mild conditions.

  • 出版日期2008-10