Direct analysis of silica by means of solid sampling graphite furnace atomic absorption spectrometry

作者：Resano M^*; Mozas E; Crespo C; Perez J; Garcia Ruiz E; Belarra M A

来源：Spectrochimica Acta Part B: Atomic Spectroscopy , 2012, 71-72: 24-30.

DOI：10.1016/j.sab.2012.03.005

• Solid sampling
• Graphite furnace atomic absorption spectrometry
• Hazardous elements
• Analysis of silica

This paper reports on the use of solid sampling-graphite furnace atomic absorption spectrometry for the direct analysis of synthetic amorphous silica. In particular, determination of hazardous elements such As, Cd, Cr, Cu, Pb and Sb is investigated, as required by regulations of the food industry. The conclusion of the work is that, after proper optimization of the working conditions, paying particular attention to the atomization temperature and the use of proper modifiers (graphite powder, HNO3 or Pd), it is possible to develop suitable procedures that rely on the use of aqueous standard solutions to construct the calibration curves for all the elements investigated. The proposed method shows important benefits for the cost-effective analysis of such difficult samples in routine labs, permitting fast screening of those elements that are very rarely present in this type of sample, but also accurate quantification of those often found, while offering low limits of detection (always below 0.1 mg g(-1)) that comply well with legal requirements, and precision levels that are fit for the purpose (approx. 6-9% R.S.D.).

• 出版日期2012-6