The influence of the type of N dopping on the performance of bifunctional N-doped ordered mesoporous carbon electrocatalysts in oxygen reduction and evolution reaction

作者：Li, Meng; Liu, Ziwu^*; Wang, Fang; Xuan, Jinjin

来源：Journal of Energy Chemistry, 2017, 26(3): 422-427.

DOI：10.1016/j.jechem.2017.01.004

• Nitrogen-containing mesoporous carbon
• Nitrogen species
• Bifunctional electrocatalysts
• Oxygen reduction reaction
• Oxygen evolution reaction

To develop more ideal bifunctional heteroatom-doped carbon electrocatalysts toward the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) for regenerative fuel cells and rechargeable metal-air batteries, herein, tobacco-derived N-containing ordered mesoporous carbon (N-OMC) electrocatalysts with different N species distributions are designed. Results indicate that the as-prepared N-OMC with more pyrrolic and pyridinic Ns exhibits much higher activities for the ORR and OER than N-OMC with more graphitic N in both acidic and alkaline media, suggesting that the increase of pyrrolic and pyridinic Ns favors the improvement of ORR and OER activities of the N-containing carbon catalysts, and showing a great potential for the designing of more effective, lower-cost ORR and OER bifunctional electrocatalysts for future regenerative fuel cells and rechargeable metal-air batteries.

• 出版日期2017-5
• 单位中国矿业大学（北京）