科研之友
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摘要
The combination of a chiral phosphoric acid with an iridium complex affords a catalyst that allows for highly enantioselective hydrogenation of imines. Mechanistic studies suggest that the hydrogenation proceeds through a ternary transition state at the hydride-transfer step, in which the organocatalyst interacts with both the hydride donor and acceptor.
- 出版日期2014-6
- 单位陕西师范大学
