Dodecanuclear [Mn-6(III) Ln(6)(III)] species: synthesis, structures and characterization of magnetic relaxation phenomena

作者：Tziotzi Thomais G; Tzimopoulos Demetrios I; Lis Tadeusz; Inglis Ross^*; Milios Constantinos J

来源：Dalton Transactions, 2015, 44(26): 11696-11699.

DOI：10.1039/c5dt01695a

The use of H3L (= 2-(beta-naphthalideneamino)-2-hydroxymethyl-1- propanol) in mixed-metal manganese-lanthanide carboxylate cluster chemistry has led to the isolation of two new dodecametallic heteronuclear isostructural [Mn-6(III) Ln(6)(III)] complexes (Ln = Gd, Dy), with the Dy analogue displaying temperature and frequency dependent out-of-phase signals suggesting possible single molecule magnetism behaviour.

• 出版日期2015