A hybrid polyoxometalate-organic molecular catalyst for visible light driven water oxidation

作者：Zhang, C.; Lin, X.; Zhang, Z.; Long, L. -S.; Wang, C.; Lin, W.^*

来源：Chemical Communications, 2014, 50(78): 11591-11594.

DOI：10.1039/c4cc03487b

• CRYSTAL-STRUCTURE
• PHOTOSYSTEM-II
• COBALT
• COMPLEXES
• OXIDES
• XPS
• STABILITY
• REDUCTION
• PHOSPHATE
• EVOLUTION

A novel organic-inorganic hybrid monocapped/bicapped Keggin structure [Co-II(bpy)(3)](6)(H(2)bpy)[(Co(II)bpy)(2)((PMo8Mo4O40)-Mo-VI-O-V)](3) [(Co(II)bpy)((PMo8Mo4O40)-Mo-VI-O-V)]center dot 16H(2)O (bpy = 2,2'-bipyridine) was synthesized and shown to be an efficient visible light-driven catalyst for water oxidation.

• 出版日期2014
• 单位厦门大学