科研之友
微信
新浪微博
Facebook
分享链接
摘要
Several alkyl- and vinylsilanes were prepared through the copper(I)-catalyzed conjugate silylation of alpha,beta-unsaturated compounds. Optimal reaction conditions were first investigated to realize the conjugate addition of a nucleophilic silicon species to poorly electrophilic acceptors such as phenylvinyl sulfone by cleavage of the SiSi bond of a disilane reagent. The scope of this reaction was extended to various electrophiles bearing different electron-withdrawing groups and afforded the desired substituted alkyl- and vinylsilanes. Among the wide range of commercially available disilanes, the reactivities of alkyl-, aryl-, and ethoxydisilane were also examined.
- 出版日期2012-9
