作者:Luca Oana R; Konezny Steven J; Blakemore James D; Colosi Dominic M; Saha Shubhro; Brudvig Gary W; Batista Victor S*; Crabtree Robert H
来源:New Journal of Chemistry, 2012, 36(5): 1149-1152.
DOI:10.1039/c2nj20912h
摘要
A Ni-II complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.