A supramolecular Co(II)(14)- metal-organic cube in a hydrogen-bonded network and a Co(II)-organic framework with a flexible methoxy substituent

作者：Mondal Suvendu Sekhar; Bhunia Asamanjoy; Kelling Alexandra; Schilde Uwe; Janiak Christoph; Holdt Hans Juergen^*

来源：Chemical Communications, 2014, 50(41): 5441-5443.

DOI：10.1039/c3cc49698h

The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO3)(2.) 6H(2)O under solvothermal conditions in DMF, a MOF, IFP-8 and a hydrogen-bonded network consisting of tetradecanuclear Co(II)(14)-metal organic cube (1) are achieved. 1 shows the bcu net with 14 cobalt atoms.

• 出版日期2014