Nitrogen doped TiO2 for hydrogen production under visible light irradiation

作者：Villa Katherine; Black Ashley; Domenech Xavier; Peral Jose^*

来源：Solar Energy, 2012, 86(1): 558-566.

DOI：10.1016/j.solener.2011.10.029

• Hydrogen production
• TiO2
• Nitrogen doping
• Visible light
• Deactivation

Heterogeneous photocatalytic production of H-2 from water by visible light activation of N-doped TiO2 samples has been studied. Two different TiO2 samples (Degussa P25 and a sol-gel prepared powder) and two nitrogen sources (urea and NH4NO3) have been selected to produce several catalyst combinations. In all cases, the platinization of the TiO2 surface dramatically improved the H-2 generation efficiency. Photonic and energy efficiencies associated to the production of hydrogen are reported. They turned out to be clearly low (below 1% under visible light irradiation). The performance of the same samples improved if UVA light irradiation was used. The N-doping had no a noticeable detrimental effect on the catalyst performance under UVA irradiation. Reutilization experiments showed a clear deactivation of the catalytic activity, especially between the 1st and 2nd experiments, and parallel to this deactivation there was always a nitrogen leakage to the solution in the form of NH4+, a fact that hinders the practical application of the N-doped catalysts.

• 出版日期2012-1