Non-conjugated anthracene derivatives and their mechanofluorochromic properties

作者：Liu, Shuai; Liu, Lixia; Liang, Cheng; Peng, Ying; Huang, Shuangping; Li, Xiaotong; Sun, Meng^*; Wang, Xiaoji^*

来源：Research on Chemical Intermediates, 2018, 44(7): 3923-3931.

DOI：10.1007/s11164-018-3331-2

• Anthracene
• Luminescence
• Stimuli-response

A series of non-conjugated methylene-anthracene Schiff base derivatives (DNCAs) were designed and synthesized. Photoluminescence emission spectra indicated that DNCA-4 and DNCA-12 showed obviously mechanofluorochromic properties, and distinctive 26- and 37-nm hypochromic shifts were observed, respectively. The experiment results revealed that there is no specific relationship between alkoxy chain lengths and their stimuli-response behavior. The PXRD profiles demonstrated a transformation from crystalline to amorphous state upon grinding.

• 出版日期2018-7
• 单位江西科技师范大学