科研之友
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摘要
N- and P-donor derivatives have been prepared by function-alization of a readily available norbornene precursor. Palladium catalytic systems containing these new ligands were applied in allylic Substitution, and yielded high activities and excellent enantioselectivities for the allylic alkylation and amination reactions (ee up to 97%). A full coordination analysis of the catalytic precursors including modelling studies was also carried out.
- 出版日期2010-2
