New polymeric sulfide-borane complexes: convenient hydroborating and reducing reagents

作者:Smith Keith*; Balakit Asim A; Pardasani Ramchand T; El Hiti Gamal A
来源:Journal of Sulfur Chemistry, 2011, 32(4): 287-295.
DOI:10.1080/17415993.2011.590489

摘要

New polymeric borane adducts have been synthesized from polymeric sulfides, which are solids with a minimal odor. Adducts containing a high concentration of borane have significant stability and are soluble in tetrahydrofuran. They act as hydroborating and reducing reagents with behavior similar to that of borane-methyl sulfide, making them attractive borane sources.
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  • 出版日期2011