New perspectives in hydrogen storage based on RCH2NH2/RCN couples

作者:Grellier M*; Sabo Etienne S
来源:Dalton Transactions, 2014, 43(17): 6283-6286.
DOI:10.1039/c3dt53583e

摘要

A recent breakthrough in primary amine dehydrogenation by an oxidant-free process, and without any hydrogen acceptor, opens the possibility for RCH2NH2/RCN couples to be considered as potential hydrogen energy carriers. Both hydrogenation and dehydrogenation processes can be catalysed by ruthenium complexes under rather mild conditions. This emerging exciting approach could be the starting point for the development of valuable economical systems.

  • 出版日期2014