A novel loose-NF membrane based on the phosphorylation and cross-linking of polyethyleneimine layer on porous PAN UF membranes

作者：Li, Ping; Wang, Zhan^*; Yang, Libin; Zhao, Shuang; Song, Peng; Khan, Bushra

来源：Journal of Membrane Science, 2018, 555: 56-68.

DOI：10.1016/j.memsci.2018.03.018

• Loose-NF composite membrane
• Phosphorylation of polyethyleneimine
• Coordinative cross-linking
• Dye/salt separation
• Textile wastewater treatment

In this study, a novel loose-NF membrane was fabricated by coating the polyethyleneimine (PEI) layer on a hydrolyzed polyacrylonitrile (HPAN) ultrafiltration membrane, followed by phosphorylation with inositol hexaphosphate (IP6) and cross-linking process. The cross-linked network was constructed by the coordinative cross-linking of Fe (III) ion and phos-(PEI), and the electrostatic attraction of PEI and IP6. At the optimized fabricating conditions, the loose-NF membrane exhibited both high rejection to dyes and transmission to different salts. The rejections of 0.1 g/L methyl blue (MB), congo red (GR), acid fuchsin (AF) and crystal violet (CV) aqueous solutions respectively were 99.92%, 99.53%, 98.99% and 92.86%, and the corresponding fluxes were 11.54, 10.96, 11.40 and 11.76 Lm(-2) h(-1) at operating pressure of 0.2 MPa. Meanwhile, the membrane exhibited low rejections to different salt solutions with the order of MgCl2 (30.51%) > MgSO4 (20.57%) > NaCl (7.46%) > Na2SO4 (5.89%) and fluxes around 19 Lm(-2) h(-1) at 0.2 MPa. Moreover, the prepared membrane possessed high stability for dealing with biologically treated textile effluent (100 h).

• 出版日期2018-6-1
• 单位北京工业大学