Disorder effects on the static scattering function of star branched polymers

作者：Blavatska V^*; von Ferber C; Holovatch Yu

来源：Condensed Matter Physics, 2012, 15(3): 33603.

DOI：10.5488/CMP.15.33603

• polymers
• structural disorder
• universality
• renormalization group

We present an analysis of the impact of structural disorder on the static scattering function of f-armed star branched polymers in d dimensions. To this end, we consider the model of a star polymer immersed in a good solvent in the presence of structural defects, correlated at large distances r according to a power law similar to r(-a). In particular, we are interested in the ratio g(f) of the radii of gyration of star and linear polymers of the same molecular weight, which is a universal experimentally measurable quantity. We apply a direct polymer renormalization approach and evaluate the results within the double epsilon = 4 - d, delta = 4 - a-expansion. We find an increase of g(f) with an increasing delta. Therefore, an increase of disorder correlations leads to an increase of the size measure of a star relative to linear polymers of the same molecular weight.

• 出版日期2012