Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

作者：Yoshida Suguru; Yano Takahisa; Misawa Yoshihiro; Sugimura Yasuyuki; Igawa Kazunobu; Shimizu Shigeomi; Tomooka Katsuhiko; Hosoya Takamitsu

来源：Journal of the American Chemical Society, 2015, 137(44): 14071-14074.

DOI：10.1021/jacs.5b10557

A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.

• 出版日期2015-11-11