Design of supramolecular metal complex catalytic systems for petrochemical and organic synthesis

作者：Karakhanov E A; Maksimov A L^*; Runova E A; Kardasheva Yu S; Terenina M V; Kardashev S V; Skorkin V A; Karapetyan L M; Talanova M Yu

来源：Russian Chemical Bulletin, 2008, 57(4): 780-792.

DOI：10.1007/s11172-008-0117-5

• supramolecular catalytic systems
• molecular imprinting
• cyclodextrins
• calixarenes
• dendrimers
• host-guest complexes
• hydroformylation
• Wacker oxidation
• aromatics coupling
• rhodium complexes
• palladium complexes

Specific features of the behavior of the supramolecular metal complex catalysts based on calixarenes, cyclodextrins, and dendrimers in the reactions of hydroformylation, Wacker oxidation, hydroxylation of aromatics, 2-naphthol coupling, and oxidative coupling of styrenes and benzene were studied. The factors affecting the catalytic activity and selectivity are discussed.

• 出版日期2008-4