Non-hydride systems of the main group elements as hydrogen storage materials

作者：Langmi Henrietta W; McGrady G Sean^*

来源：Coordination Chemistry Reviews, 2007, 251(7-8): 925-935.

DOI：10.1016/j.ccr.2006.09.009

• hydrogen storage materials
• lithium nitride
• ammonia borane
• zeolites
• carbon nanotubes

This review surveys the state of the art in non-hydride hydrogen storage materials composed of the elements B, C, N, O, Si, and Al. In the nitrogen-based systems Li3N and NH3BH3 hydrogen is chemically bound in the formal oxidation states +1 and -1, whereas carbon nanotubes and aluminosilicate-based zeolites adsorb or encapsulate molecular H-2. The advantages and drawbacks of each system are discussed, and comparisons between them are made where appropriate.

• 出版日期2007-4