Facile synthesis of palladium nanowires by a soft templating method

作者:Siril Prem Felix; Lehoux Anais; Ramos Laurence; Beaunier Patricia; Remita Hynd*
来源:New Journal of Chemistry, 2012, 36(10): 2135-2139.
DOI:10.1039/c2nj40342k

摘要

Very long and thin monocrystalline Pd nanowires were synthesized by decomposition using hydrazine vapour treatment of Pd-2(DBA)(3) confined in the oil phase of a hexagonal mesophase. The mesophase is composed of toluene-swollen tubes, doped with the Pd precursor, stabilized by a monolayer of surfactant and cosurfactant molecules, and arranged on a triangular lattice in water. Our synthesis is selective and the experiments show that both the confinement and the nature of the surfactant are essential to obtain these Pd nanowires.

  • 出版日期2012