Absorption, fluorescence and second harmonic generation in Cr3+-doped BiB3O6 glasses

作者:Kuznik, W.; Fuks-Janczarek, I.; Wojciechowski, A.; Kityk, I. V.*; Kiisk, V.; Majchrowski, A.; Jaroszewicz, L. R.; Brik, M. G.; Nagy, G. U. L.
来源:Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2015, 145: 325-328.
DOI:10.1016/j.saa.2015.03.041

摘要

Synthesis, spectral properties and photoinduced nonlinear optical effects of chromium-doped BiB3O6 glass are studied in the present paper. Absorption, excitation and time resolved luminescence spectra are presented and luminescence decay behavior is discussed. Detailed analysis of the obtained spectra (assignment of the most prominent spectral features in terms of the corresponding Cr3+ energy levels, crystal field strength Dq, Racah parameters B and C) was performed. A weak photostimulated second harmonic generation signal was found to increase drastically due to poling by proton implantation in the investigated sample.