mu-Glycine-kappa O-2 : O '-di-mu-sulfido-bis[(glycinato-kappa N-2,O)oxidomolybdenum(V)]

作者：Li Ya Min^*; Li Yong Hong; Zhai Cui Ping

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M2931-U683.

DOI：10.1107/S1600536807054761

In the title compound, [Mo-2(C2H4NO2)(2)O2S2(C2H5NO2)], the two Mo-V atoms are bridged by two mu(2)-S atoms and one glycine ligand in an O:O'-bidentate mode. In addition, each MoV atom is bonded to one terminal oxygen ligand and chelated by one N,O-bidentate glycinate ligand, resulting in a distorted octahedral coordination. A complex hydrogen-bonding network is constructed by intermolecular N-H center dot center dot center dot O hydrogen bonds.

• 出版日期2007-12
• 单位河南大学