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摘要
A new type of hybrid materials with montmorillonite and triazene polyacrylates as poly [(1-(phenyl)-3-(2 acryloyloxyethyl)-3-methyl triazene-1-co-methyl methacrylate] (PAT(1)) and poly [1-(para chloro-phenyl)-3-(2 acryloyloxyethyl)-3-methyl triazene-1-co-methyl methacrylate] (PAT(2))) has been successfully prepared using the solution-intercalation film-casting technique. The nanoscale silicate layers are intercalated in the polyacrylates matrix as resulted by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Additional information regarding the structure of triazene polyacrylates nanocomposites (PAT(1)/MMT and PAT(2)/MMT) were obtained by FT-IR analysis, atomic force microscopy (AFM) and thermal decomposition behavior, the latter indicating a higher thermal stability compared to the starting triazene copolymers.
- 出版日期2009-5
